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Kinetics: The study of the reaction rate and mechanism. Equilibrium: Reaction does not proceed to completion, instead, it reaches a balanced state of forward and reverse reactions.
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Hammond-Leffler postulate: The TS is more like the reactant or product that is closer in energy; endothermic TS is like the product, exothermic TS is like the reactant. Kinetic vs. Solvent effects: A solvent may stabilize an intermediate, decreasing Ea and increasing the rate of the reaction. Charged-complexes are stabilized by polar solvents.
For cyclic, cis more stable. Factors which influence properties: chain length, branching vs. Layout: Andre Brisson Note: Due to the condensed nature of this chart, use as a quick reference guide, not as a replacement for assigned course work. The reaction reagents are noted for illustrative purposes only; this should not serve as guide for lab experiment procedures.
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